Excimer formation in the interlayer region of arene-derivatized zirconium phosphonates.

نویسندگان

  • Jay C Amicangelo
  • Willem R Leenstra
چکیده

Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 125 48  شماره 

صفحات  -

تاریخ انتشار 2003